论文题目: | Naphthalenones from a Perenniporia sp Inhabiting the Larva of a Phytophagous Weevil, Euops chinesis |
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作者: | Feng, Y; Wang, L; Niu, SB; Li, L; Si, YK; Liu, XZ; Che, YS |
联系作者: | Liu, XZ |
刊物名称: | JOURNAL OF NATURAL PRODUCTS |
期: | 7 |
卷: | 75 |
页: | 1339-1345 |
年份: | 2012 |
影响因子: | 3.128 |
论文下载: | |
摘要: | The new naphthalenone derivatives perenniporides A-D (1-4) were isolated from solid cultures of a fungus Perenniporia sp. inhabiting the larva of Euops chinesis, a phytophagous weevil with high host specificity to the medicinal plant Fallopia japonica. The structures of 1-4 were elucidated primarily by NMR experiments, and 1 was confirmed by X-ray crystallography. The absolute configuration of 1 and 2 was assigned by electronic circular dichroism (ECD) calculations, whereas that of the C-10 tertiary alcohol in 3 was deduced via the CD data of the in situ formed [Rh-2(OCOCF3)(4)] complex and supported by the ECD data Compound 1 showed antifungal activity against five plant pathogens. |
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